Cooling of melts: kinetic stabilization and polymorphic transitions in the KInSnSe 4 system.
نویسندگان
چکیده
Through a flame-melting/rapid-cooling process, metastable forms of solid state compounds can be discovered. We describe here an example where both slow and rapid crystallizations of a stoichiometric "KInSnSe(4)" melt give rise to kinetic forms of KInSnSe(4). These forms (alpha- and beta-) convert to the thermodynamically stable gamma-form upon heating below the melting point.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 43 7 شماره
صفحات -
تاریخ انتشار 2004